Abstract
The importance of the nitrification‐mediated nitrosation reaction between NO2 − and soil organic matter is difficult to assess: because NO2 − is very unstable in the presence of organic compounds, many unwanted chemical reactions may occur during extraction, incubation and analysis. Buffered samples containing both NO2 − and organic compounds of interest for that nitrosation reaction were incubated and analyzed for their N‐content by various conventional laboratory methods. The reliability of these methods was evaluated and major problems were identified.