Study of complexation between perrhenate ion and N-methyl-N-vinylacetamide and N-methyl-N-vinylamine copolymers in aqueous solutions by fast monolith high-performance liquid chromatography (HPLC)

N. I. GorshkovDepartment of Water Soluble Polymers, Federal State Budgetary Institution of Science Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, RussiaCorrespondence[email protected]
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I. I. GavrilovaDepartment of Water Soluble Polymers, Federal State Budgetary Institution of Science Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, RussiaView further author information

V. D. KrasikovDepartment of Water Soluble Polymers, Federal State Budgetary Institution of Science Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, RussiaView further author information

E. F. PanarinDepartment of Water Soluble Polymers, Federal State Budgetary Institution of Science Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia;Department of the Medical Physics, St. Petersburg Peter the Great Polytechnical Institutе of the Russian Federation, St. Petersburg, RussiaView further author information

ABSTRACT

Complexation between perrhenate ion and N-methyl-N-vinylacetamide and N-methyl-N-vinylamine copolymers in aqueous solutions was studied by high-performance liquid chromatography on monolith ultrashort columns. It was demonstrated that complexation has slow kinetics and strongly depends on the length of alkyl substituent.

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Funding

This research was supported by the Russian Foundation of Basic Research 16-03-00584, 15-9340, 15-03-04170.

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Study of complexation between perrhenate ion and N-methyl-N-vinylacetamide and N-methyl-N-vinylamine copolymers in aqueous solutions by fast monolith high-performance liquid chromatography (HPLC)

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Study of complexation between perrhenate ion and N-methyl-N-vinylacetamide and N-methyl-N-vinylamine copolymers in aqueous solutions by fast monolith high-performance liquid chromatography (HPLC)

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