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Articles

Two new 5/6/6 polyketide-amino acid hybrids from a genetic mutant of Periconia sp. F-31

, , , , &
Pages 535-541 | Received 17 Jan 2021, Accepted 08 Jun 2021, Published online: 28 Jun 2021
 

Abstract

Peridecalins C and D (1 and 2), one decalin and one oxygen-decalin containing polyketide-amino acid hybrids with 5/6/6 ring system, was isolated from a genetic mutant of Periconia sp. F-31. Their structures were elucidated through extensive spectroscopic data analysis, including 1 D/2D NMR and HR-MS spectra. Biosynthetically, two proposed Diels-Alder reactions are supposed to be involved in the skeleton construction of 1 and 2.

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

This work was financially supported by National Natural Science Foundation of China (No. 81773607).

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