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Abstract
Phosphorescence measurements were performed for 6H-benzo[cd]-pyren-6-one (l), 2-nitro-benzo[hi]chrysen- 13-one (2), 2-bromo-di-benzo[a, de]anthracen- 13-one (3), and 7H-benzo[hi]chrysen-7-one (4) in an ethanol-ether-toluene mixed solution and the character of their lowest excited triplet (T1) states were investigated. The phos horescence of the compounds appears at about 5,200 – 6,000 cm−1 to the red of their fluorescence, indicating that the T, states have ππ* character. On the other hand, the short phosphorescence lifetimes, 10 – 60 ms, suggest nπ* transitions. Such a duality of the T1 state seems to be characteristic of large polycyclic aromatic ketones. The polarized emission study revealed that the duality is ascribed to strong mixing of ππ* and nπ* natures.