Sorption of Pyrene to Two Estonian Soils

Abstract

Two typical Estonian soils, Brown pseudopodzolic and Rendzina, were used for sorption studies with pyrene. The soil samples were subjected to a variety of chemical and physical tests. The specific surface area reached 3.05 m² g⁻¹ for Rendzina, and 0.87 m² g⁻¹ for Brown pseudopodzolic soil. The Rendzina type of soil was characterized also by a high organic matter content (22.9%) compared with the Brown pseudopodzolic soil (6.64%). A batch technique was used to perform all adsorption studies. K_oc values 2.7 × 10⁴ mg g⁻¹ for Rendzina and 4.5 × 10⁴ mg g⁻¹ for Brown pseudopodzolic were obtained. The results suggets that pyrene sorption behaviour could be in some instances mainly influenced by the composition of organic compounds in the soil, not so much by the overall organic matter content. Also the mineral part of the soil can have a impact to pyrene sorption through Ca-binded humic substances.

Key Words:

• pyrene
• soil
• adsorption
• isotherms