ABSTRACT
Four different mercaptoalkyl-substituted calixarene derivatives (5,11,17,23-tetra-tert-butyl-25,27-bis(3-mercaptopropoxyl)-26,28-dihydroxycalix[4]arene, 25,27-bis(3-mercaptopropoxyl)-26,28-dihydroxycalix[4]arene, 25,27-bis(5-mercaptopentanoxyl)-26,28-dihydroxycalix[4]arene and 5,17-di-tert-butyl-11,23-di-carboxyl-26,28-bis(3-mercaptopropoxyl)-25,27-di-hydroxycalix[4]arene) were synthesized. Their structures were characterized by Fourier transform infrared spectroscopy (FTIR), 1H and 13C NMR spectroscopy, and elemental analysis techniques. Moreover, their extraction capabilities at different parameters such as pH, shaking speed, and shaking time were examined toward dichromate ions. Results implied that all mercaptoalkyl-substituted calixarene derivatives showed an extraction capability toward dichromate anion while the carboxyl-functionalized calixarene-marcapto-alkyl derivative exhibited the highest extraction capability.
Funding
Authors would like to thank the European Union through the COST Action CM1202 “Supramolecular photocatalytic water splitting (PERSPECT-H2O)” and the Scientific and Technological Research Council of Turkey (TUBITAK Grant Number 113T022) for the financial support of this research.