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Polycyclic Aromatic Compounds Volume 9, 1996 - Issue 1-4
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OCCURRENCE: EMISSIONS, AIR, SOILS AND SEDIMENTS

Determination of Vapour Pressure and Related Thermodynamic Properties of Polycyclic Aromatic Compounds

H. A. J. Govers Department of Environmental and Toxicological Chemistry, ARISE, University of Amsterdam, Nieuwe Achtergracht 166, 1018, WV Amsterdam, The Netherlands
,
E. Ruts Department of Environmental and Toxicological Chemistry, ARISE, University of Amsterdam, Nieuwe Achtergracht 166, 1018, WV Amsterdam, The Netherlands
,
F. W.M. Van Der Wielen Department of Environmental and Toxicological Chemistry, ARISE, University of Amsterdam, Nieuwe Achtergracht 166, 1018, WV Amsterdam, The Netherlands
&
A. G. Van Haelst Department of Environmental and Toxicological Chemistry, ARISE, University of Amsterdam, Nieuwe Achtergracht 166, 1018, WV Amsterdam, The Netherlands
Pages 75-83 | Published online: 22 Sep 2006
 
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Abstract

A gas-liquid chromatographic (GLC) method is presented for determination of (sub-cooled) liquid vapour pressure, heat of vaporization and gas-liquid heat capacity differences of low-volatility organic compounds. Values obtained for unsubstituted and chlorine on-ring plus nitrogen in-ring substituted polycyclic aromatic compounds compare favourably with those obtained via other experimental and theoretical methods. The method allows for the determination of properties of large numbers of compounds and the distinction between isomers.

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