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Polycyclic Aromatic Compounds Volume 16, 2000 - Issue 1-4
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Mechanisms of Action

Quantitative Aspects of the Effects of Halide and Azide Ions on the Acid-Catalyzed Hydrolysis of (±)-7β,8α-Dihydroxy-9α,10α-Epoxy-7,8,9,10-Tetrahydrobenzo[a]Pyrene

Bin Lin Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, Baltimore, MD, 21228, USA
,
Lanxuan Doan Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, Baltimore, MD, 21228, USA
,
Haruhiko Yagi Laboratory of Bioorganic Chemistry, National Institutes of Health, Bethesda, MD, 20892
,
Donald M. Jerina Laboratory of Bioorganic Chemistry, National Institutes of Health, Bethesda, MD, 20892
&
Dale Whalen Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, Baltimore, MD, 21228, USA
Pages 79-88 | Published online: 22 Sep 2006
 
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Abstract

Mechanisms of the acid-catalyzed reactions of (±)-7β,8α-dihydroxy-9α,10α-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene (1) in 1:9 dioxane-water solutions containing varying concentrations of KCl, KBr, NaI, NaN3 and NaClO4 are discussed.

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