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Radiation Effects and Defects in Solids
Incorporating Plasma Science and Plasma Technology
Volume 149, 1999 - Issue 1-4
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1 Colour Centres

ESR of trapped-electron Fe+ centres in chlorinated SrCl2 crystals

S. V. Nistor Institute of Atomic Physics, National Institute of Materials Physics, 76900, Bucharest-Magurele, Romania; Physics Department, University of Antwerp (UIA), Universiteitsplein 1, B-2610 Antwerpen, Belgium
,
M. Stefan Institute of Atomic Physics, National Institute of Materials Physics, 76900, Bucharest-Magurele, Romania; Physics Department, University of Antwerp (UIA), Universiteitsplein 1, B-2610 Antwerpen, Belgium
,
A. Bouwen Physics Department, University of Antwerp (UIA), Universiteitsplein 1, B-2610 Antwerpen, Belgium
&
D. Schoemaker Physics Department, University of Antwerp (UIA), Universiteitsplein 1, B-2610 Antwerpen, Belgium
Pages 203-207 | Received 06 Jul 1998, Published online: 19 Aug 2006
 
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Abstract

Two Fe+ centres have been identified by ESR after X-ray irradiation at 80 K of chlorinated SrCl2: Fe2+ crystals. Both centres, with tetragonal symmetry, consist of an Fe+ ion with a neighbouring charged defect along the ⟨001⟩ symmetry axis. The substitutional Fe+ ion of the Fe+(I) centre is strongly off-centre displaced in the Fe+ (II) centres, in the middle of a square of four nearest neighbour chlorine ligands.

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