Ammonium Eneselenolates: Stereochemical and Spectroscopic Properties

Toshiaki Murai Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido, Gifu, 501-1193, Japan

Shuuya Hayakawa Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido, Gifu, 501-1193, Japan

Youhei Miyazaki Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido, Gifu, 501-1193, Japan

Shinzi Kato Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido, Gifu, 501-1193, Japan

Abstract

The efficient generation and alkylation of ammonium ene selenolates have been described. The synthesis of ketene seleno thioacetals having a variety of functional groups was attained. The stereoselectivity of the generation of ammonium eneselenolates was compared between selenoic acid O-esters and selenothioic acid S-esters.

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Ammonium Eneselenolates: Stereochemical and Spectroscopic Properties

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