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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 176, 2001 - Issue 1
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Original Articles

Synthesis and Photochemistry of 2-(α-Furyl)-2-(α-Thienyl) SHexamethyltrisilane

Yu-Mei Luo Department of Chemistry, Shanghai Teachers University, 100 Guilin Lu, Shanghai, 200234, China
&
He-bai Shen Ping Zhou Department of Chemistry, Shanghai Teachers University, 100 Guilin Lu, Shanghai, 200234, China
Pages 69-76 | Published online: 23 Oct 2006
 
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Abstract

The synthesis of 2-(α-furyl)-2-(α-thienyl)hexamethyltrisilane is described. Photolysis of 2 in the presence of cyclohexene and methanol led to apparent radical reaction. It is proposed that the sulfur atom of thienyl group strongly stabilized an initially formed silyl radical. This idea was supported by identifying typical radical reaction products.

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