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Original Articles

Cyclobutadiene Dianion Dilithium: a New Aromatic Ring System

Pages 51-58 | Received 17 Jul 2000, Published online: 30 Apr 2008
 

Abstract

The reaction of tetrakis(trimethylsilyl)- (or cis-diphenyl) cyclobutadiene cobalt complexes with lithium metal in THF at room temperature produced the dilithium salts of tetrakis(trimethylsilyl)- (or cis-diphenyl) cyclobutadiene dianion, which were isolated as pale yellow (or pale orange) solids stable in the absence of air. NMR spectra and X-ray crystallography of these dianions provide the evidence for an aromatic character with a six π-electron system.

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