Abstract
The reaction of tetrakis(trimethylsilyl)- (or cis-diphenyl) cyclobutadiene cobalt complexes with lithium metal in THF at room temperature produced the dilithium salts of tetrakis(trimethylsilyl)- (or cis-diphenyl) cyclobutadiene dianion, which were isolated as pale yellow (or pale orange) solids stable in the absence of air. NMR spectra and X-ray crystallography of these dianions provide the evidence for an aromatic character with a six π-electron system.