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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 177, 2002 - Issue 4
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Original Articles

Trifluoromethylthiolation of Trimethylsilyl Enol Ethers

S. Munavalli Geo-Centers, Inc., Gunpowder Branch, Aberdeen Proving Ground, Maryland
,
D. K. Rohrbaugh Edgewood Chemical Biological Center, U.S. Army, Aberdeen Proving Ground, Maryland
,
D. I. Rossman Edgewood Chemical Biological Center, U.S. Army, Aberdeen Proving Ground, Maryland
,
W. G. Wagner Edgewood Chemical Biological Center, U.S. Army, Aberdeen Proving Ground, Maryland
&
H. D. Durst Edgewood Chemical Biological Center, U.S. Army, Aberdeen Proving Ground, Maryland
Pages 1021-1031 | Published online: 27 Oct 2010
 
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Abstract

The treatment of bis-(1,2-trimethylsilyloxy)-1-cyclobutene, 1-(1-trimethylsilyloxy)cyclpentene and 1-(1-trimethylsilyloxy)cyclohexene with trifluoromethylsulfenyl chloride has been found to furnish trifluoromethylthiolated carbonyl derivatives.

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Related Research Data

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