Advanced search
Publication Cover
Phosphorus, Sulfur, and Silicon and the Related Elements Volume 177, 2002 - Issue 6-7
Submit an article Journal homepage
21
Views
16
CrossRef citations to date
0
Altmetric
Original Articles

Self-Assembly of the Complexes of Bipodal Thiophosphorylated Thioureas

Nail G. Zabirov Department of Chemistry, Kazan State University, Kazan, Russia
,
Vasiliy V. Brusko Department of Chemistry, Kazan State University, Kazan, Russia
,
Alexander Y. Verat Department of Chemistry, Kazan State University, Kazan, Russia
,
Dmitry B. Krivolapov A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan, Russia
,
Igor A. Litvinov A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan, Russia
&
Rafael A. Cherkasov Department of Chemistry, Kazan State University, Kazan, Russia
Pages 1869-1872 | Published online: 27 Oct 2010
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

N-Thiophosphorylated thioureas, of general formula [(i-PrO) 2 P(S)NHC(S)] 2 Z (Z = f , y -diamino(oxy)alkyl or 1,10-diaza-18-crown-6), in the form of potassium salts, react with a number of soft ions (Cd 2+ , Zn 2+ , Co 2+ , Ni 2+ , Pd 2+ ) to form novel dimeric complexes. The cadmium (Z = HN(CH 2 ) 2 NH), palladium (Z = HN(CH 2 ) 2 O(CH 2 ) 2 NH), and cobalt (Z = 1,10-diaza-18-crown-6) complexes were analyzed by x-ray crystallography. In the former complex, crown cavities remain free. This fact will allow us to obtain "guest-host" complexes with alkali metal cations.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Halogen anion-induced formation of [(PdLX)2] (X = Cl−, Br−, I−) vs. [PdL2] (L = [6-MeO(O)CC6H4NHC(S)NP(S)(OiPr)2]−): Reversible photoinduced cis/trans isomerization of [PdL2]
Source: Royal Society of Chemistry (RSC)
Synthesis and characterization of crown ether-containing N-phosphorylated thioureas RC(S)NHP(O)(OiPr)2 (R = 1-aza-15-crown-5, 1-aza-12-crown-4) and their Co(II) and Ni(II) complexes
Source: (:unav)
Complexes of Crown Ether-Containing N-Phosphorylated Thioamides and Thioureas with CoII, ZnII and PdII Cations
Source: (:unav)
Cobalt(II) Complexes with N-Thioacylamidophosphates and 2,2′-Bipyridyl and 1,10-Phenathroline. Crystal Structures, Solution 1H NMR Spectral and Magnetic Properties
Source: Wiley
First paramagnetic PdII complex with a PdN4S2 coordination core
Source: (:unav)
Rich Magnetic Chemistry of Cobalt(II) Complexes withN-Phosphorylthioureas. Crystal Structure and Solution1H NMR Spectral Properties
Source: Wiley
The influence of an intramolecular hydrogen bond on the 1,3-N,S-coordination of crown ether-containing N-phosphorylthiourea with NiII
Source: Royal Society of Chemistry (RSC)

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.