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Original Articles

Reactions of Trifluoromethylsulfenyl Chloride and Trifluoromethylthiocopper with 2-(Trimethylsilyl)thiazole

, , , &
Pages 2465-2470 | Published online: 27 Oct 2010
 

Abstract

The treatment of 2-(trimethylsilyl)thiazole with trifluoromethylsulfenyl chloride furnishes the expected 2-(trifluoromethylthio)thiazole in satisfactory yields along with the ring contraction product of the azirine-type. However, the reaction of 2-bromothiazol with trifluoromethylthiocopper gives poor yields of the above compound. The mechanism of formation and the mass spectral characterization of the products are presented in this article.

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