Synthesis and NMR Spectroscopic Study of a New Bis(aminophosphonate) with Terminal Furyl Groups

Abstract

1,3-Bis[ N -methyl(diethoxyphosphonyl)-1-(2-furyl)]diaminobenzene has been synthesized through the addition of diethyl phosphite to the Schiff base N , N '-difurfurylidene- m -phenylenediamine. The compound has been characterized by elemental analysis, TLC, IR, and 1 H, 13 C, and 31 P NMR spectra. The NMR studies show that the reaction product is a mixture of two diastereomers ( meso and racemic forms). The 31 P NMR data revealed 61% content for the predominant and 39% for the minor form.

Keywords:

• Aminophosphonic Acids
• Furan Derivatives
• Nmr Spectra
• Schiff Bases