Neue Thiosubstituierte Butadien- Und Butenin Verbindungen Aus Hexachlorbutenen Und Thiolen

Abstract

2,3-Di-H-butene compound 1 gave compounds 3a-f , 4a , 4e , and 5a-d in the presence of thiols 2a-f and Et 3 N (or NaOH). Compound 7e was obtained from the reaction of 1,3-Di-H-butene 6 with naphthylthiol in DMF. In the presence of NaOH, compound 6 and 2 mmol of thiol 2g in EtOH gave compounds 8 , 9 , 10 , and 11 .

Keywords:

• 1,3-Tetrachlorobutene
• 2,3-Di-H-tetrachlorobutene
• Bis-, Tris-, And Tetrakis-(organylthio)-butadienes
• Mono- And Bis-(organylthio) Butenynes
• Thiols