Phosphorylation of Allyl Halides with White Phosphorus

Svetlana Malysheva A. E. Favorsky Irkutsk Institute, Chemistry of the Russian Academy of Sciences, Irkutsk, Russia

Boris Sukhov A. E. Favorsky Irkutsk Institute, Chemistry of the Russian Academy of Sciences, Irkutsk, Russia

Nina Gusarova A. E. Favorsky Irkutsk Institute, Chemistry of the Russian Academy of Sciences, Irkutsk, Russia

Svetlana Shaikhudinova A. E. Favorsky Irkutsk Institute, Chemistry of the Russian Academy of Sciences, Irkutsk, Russia

Tat'yana Kazantseva A. E. Favorsky Irkutsk Institute, Chemistry of the Russian Academy of Sciences, Irkutsk, Russia

Natal'ya Belogorlova A. E. Favorsky Irkutsk Institute, Chemistry of the Russian Academy of Sciences, Irkutsk, Russia

Vladimir Kuimov A. E. Favorsky Irkutsk Institute, Chemistry of the Russian Academy of Sciences, Irkutsk, Russia

Boris Trofimov A. E. Favorsky Irkutsk Institute, Chemistry of the Russian Academy of Sciences, Irkutsk, Russia

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Abstract

White phosphorus reacts with allyl bromide in the system KOH-dioxane-H 2 O at room temperature to form tris(propen-2-yl), bis(propen-2-yl)(E-propen-1-yl), and bis(E-propen-1-yl)(propen-2-yl)phosphine oxides in a total quantitative yield, their molar ratio being 1:0.5:0.1.

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Phosphorylation of Allyl Halides with White Phosphorus

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Phosphorylation of Allyl Halides with White Phosphorus

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