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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 181, 2006 - Issue 4
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Original Articles

Synthesis and Structure of N-Ethoxycarbonyl-N′-O-Methoxyphenylthiourea

Bi-Quan Su School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, China
,
Gai-Lan Liu School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, China
,
Li Sheng School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, China
,
Xiao-Qiang Wang School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, China
&
Liang Xian State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences, Lanzhou, China
Pages 745-750 | Received 24 Feb 2005, Accepted 15 Apr 2005, Published online: 15 Aug 2006
 
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N-ethoxycarbonyl-N′-o-methoxyphenylthiourea was synthesized and characterized by elemental analysis, TG-DTA analysis, IR, and 1H NMR spectrum, and single crystal X-ray diffraction analysis. The compound crystallizes as a planar molecule in the monoclinic space group P2(1)/c, with a = 9.690(2)Å, b = 8.595(2)Å, c = 15.944(4)Å, α = 90°, β = 106.467(4)°, γ = 90°, and Dcalc = 1.326 g/cm3 for Z = 4. Intramolecular H-bonds promote the stability of the title compound and change the coordination ability of the thiourea ligand. Intermolecular N─H…S H-bonds link pairs of two molecules.

Acknowledgments

Financial support of this work by the Science-Technology Foundation for Middle-Aged and Young Scientists of Gansu Province (No. 3YS051-A25-011) and the Foundation of Lanzhou Jiaotong University are acknowledged.

Notes

*Symmetrycodes: 1−x, -y, 2-z

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