Retrospect of Se and Te Chemistry

Retrospect of organoselenium and tellurium chemistry for these 30 years is described focusing on our novel findings in this field: (1) telluroxide elimination leading to alkenes and allylic compounds, (2) Pd-catalyzed or –mediated carbodetelluration for a new C–C bond formation, (3) synthesis of chiral diferrocenyl dichalcogenides and their use as chiral auxiliaries, (4) asymmetric selenoxide elimination for making optically active allenes and alkenes, (5) meta chloroperbenzoic acid (MCPBA) oxidation of organic selenides and tellurides leading to a substitution of a PhSe or PhTe moiety, as well as (6) preparation of chalcogen-bridged diruthenium complexes and their catalytic use for propargylic substitution reactions.

Keywords:

• Asymmetric selenoxide elimination
• carbodetelluration
• chalcogen-bridged diruthenium complex
• chiral diferrocenyl dichalcogenide
• imidation
• oxidation
• telluroxide elimination

Acknowledgments

I would like to express my grateful acknowledgement to all of my collaborators for these works. Without their enthusiastic efforts these works have not been done.