Synthese d'une Serie de 2-(F-alkyl) Thioenol Ethers

Abstract

2-(F-alkyl) enol ethers react easily with thiols. With one equivalent of the thiol, the corresponding 2-(F-alkyl) thioenol ethers were formed via an addition-elimination mechanism. With two equivalents of thiol or with one equivalent of 1,2-ethanedithiol, 2-(F-alkyl) thioacetals or 2-(F-alkyl) dithiolanes were obtained in good yields.

Keywords:

• F-alkylthioenol ethers
• F-alkylacetals
• F-alkyldithiolanes