A New Approach to The Synthesis of Phosphoranes Based on the Reaction of Benzo[d]-1,3,2-Dioxaphospholes, Having β- or γ-Unsaturated Group in a Substituent, with Compounds Containing Multiple Bonds

V. F. Mironov Kazan State University and A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, Tatarstan, Russia

L. M. Abdrakhmanova A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, Tatarstan, Russia

M. N. Dimukhametov A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, Tatarstan, Russia

L. M. Burnaeva Kazan State University, Kazan, Tatarstan, Russia

Yu. Yu. Kotorova Kazan State University, Kazan, Tatarstan, Russia

I. V. Konovalova Kazan State University, Kazan, Tatarstan, Russia

Abstract

We developed a new approach to the synthesis of phosphoranes and carba phosphatranes on the basis of the reaction of benzo[d]-1,3,2-dioxaphospholes, having β- or γ-unsaturated group in a substituent, with such compounds containing multiple bonds, such as hexafluoroacetone, chloral, and diethylacetylenedicarboxylate.

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Acknowledgments

The work is supported by Russian Foundation for Basic Research (grant 07-03-00180a).

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A New Approach to The Synthesis of Phosphoranes Based on the Reaction of Benzo[d]-1,3,2-Dioxaphospholes, Having β- or γ-Unsaturated Group in a Substituent, with Compounds Containing Multiple Bonds

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A New Approach to The Synthesis of Phosphoranes Based on the Reaction of Benzo[d]-1,3,2-Dioxaphospholes, Having β- or γ-Unsaturated Group in a Substituent, with Compounds Containing Multiple Bonds

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