Novel Heterocyclic P-Ligands: Synthesis and Application in Pt(II) Complexes

György Keglevich Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary

Andrea Kerényi Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary

Melinda Sipos Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary

Annamária Balassa Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary

Tamás Körtvélyesi Department of Physical Chemistry, University of Szeged, Szeged, Hungary

Abstract

3-Diphenylphosphino-1,2,3,6-tetrahydro- and 1,2,3,4,5,6-hexahydro-phosphinines, as well as dibenzo[c,e][1,2]oxaphosphorines (L) were prepared and used in the synthesis of the corresponding cis chelate Pt(II) complexes and PtCl₂L₂ complexes, respectively. The latter family of compounds includes 7-membered ring Pt(II) complexes.

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Acknowledgments

This project was supported by the European Union and the Hungarian State (GVOP- 3.2.2.-2004-07-0006/3.0) and jointly by the Hungarian Scientific Research Fund (OTKA, Grant No. T067679).

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Novel Heterocyclic P-Ligands: Synthesis and Application in Pt(II) Complexes

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Novel Heterocyclic P-Ligands: Synthesis and Application in Pt(II) Complexes

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