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A convenient synthetic approach for previously unknown N-H imidoylphosphonates, based on addition of dialkyl phospites to trifluoroacetonitrile, was developed. Synthetic potentialities of imines 1 existing as equilibrium mixture of E/Z isomers, were demonstrated.
Yu. V. R. Thanks INTAS for financial support (YSF Grant No. 05-109-4922.)
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