Synthesis and Complexations of a Novel Stable Carbene Bearing a Phosphorus Ylide

Shin-ya Nakafuji Department of Chemistry, Graduate School of Science, The University of Tokyo, Bunkyo-ku, Tokyo, Japan

Junji Kobayashi Department of Chemistry, Graduate School of Science, The University of Tokyo, Bunkyo-ku, Tokyo, Japan

Takayuki Kawashima Department of Chemistry, Graduate School of Science, The University of Tokyo, Bunkyo-ku, Tokyo, Japan

Abstract

Rh complexes 5 and 6 were synthesized via the titled carbine 1 . In the IR spectrum of 6 , the carbonyl stretching frequency was observed at the lower wave number among all [(carbene)Rh(CO)₂Cl] complxes reported to date, including the highest electron-donating ability of carbene 1 .

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Synthesis and Complexations of a Novel Stable Carbene Bearing a Phosphorus Ylide

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Synthesis and Complexations of a Novel Stable Carbene Bearing a Phosphorus Ylide

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