Studies on 1,10-Phenanthroline Complexes of Some Hydroxyaryltellurium Trihalides

Abstract

The synthesis and structural features of some newly synthesized 1,10-phenanthroline complexes of p-hydroxyphenyl-and 3-methyl-4-hydroxyphenyltellurium trihalides (chlorides, bromides, and iodides) are reported. The resulting complexes have been subjected to elemental analyses, conductance and cryoscopic measurements, infra-red and proton magnetic resonance spectral studies. Solution studies reveal the weak to 1:1 electrolyte type behavior of these complexes in solution. Spectral studies indicate the linkage of phenanthroline to the tellurium atom through the nitrogen atoms. Central tellurium atom in these complexes is hexa-coordinated in an octahedral way.

Keywords:

• p-Hydroxyphenyltellurium trihalides
• 3-methyl-4-hydoxyphenyltellurium trihalides
• phenanthroline complexes

The authors are thankful to Maharshi Dayanand University, Rohtak (India) for necessary facilities.