Advanced search
Publication Cover
Phosphorus, Sulfur, and Silicon and the Related Elements Volume 184, 2009 - Issue 12
Submit an article Journal homepage
31
Views
7
CrossRef citations to date
0
Altmetric
Original Articles

Synthesis, Crystal Structure, and Luminescence of a Three-Dimensional Supramolecular Compound Based on a Dinuclear Tin Cluster

Wenxiang Chai College of Materials Science and Engineering, China Jiliang University, Hangzhou, People's Republic of China
,
Li Song Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Education Ministry, Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou, People's Republic of China
,
Hangyan Shen College of Materials Science and Engineering, China Jiliang University, Hangzhou, People's Republic of China
&
Kangying Shu College of Materials Science and Engineering, China Jiliang University, Hangzhou, People's Republic of China
Pages 3212-3220 | Received 29 Oct 2008, Accepted 22 Feb 2009, Published online: 18 Nov 2009
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

A three-dimensional (3D) supramolecular compound, [(phen)LSnS]2·(H2O)2 (phen = 1,10-phenanthroline, L = mercaptoacetic acid), has been synthesized and the crystal structure was determined by a single crystal X-ray diffraction study. 1 is triclinic, space group P-1 with a = 6.695(1) Å, b = 10.929(2) Å, c = 12.117(2) Å, α = 114.55(3)°, β = 93.53(2)°, γ = 104.06(3)°, and Z = 1. The dinuclear cluster of [(phen)LSnS]2 and H2O are linked into a 3D supramolecular framework by a combination of O[sbnd]H…O, C[sbnd]H…O hydrogen bonds and π–π stacking interactions. Its luminescence property is discussed.

This research was supported by the National Natural Science Foundation of China (Projects 20701034, 50702054, 20803070, and 60808016), the Analysis and Testing Foundation of Zhejiang Province (Projects 2008F70034 and 2008F70053), the Scientific Research Fund of Zhejiang Provincial Education Department (Projects 20070358), and the Foundation for Person with Ability (2007QN01).

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

A novel heterometallic dinuclear compound: rac-pentaaqua-1κ5O-(μ-2-sulfidoacetato-1:2κ3O:O',S)bis(2-sulfidoacetato-2κ2O,S)manganese(II)tin(IV).
Source: (:unav)
A Supramolecular Framework Structure of a Novel Heterometallic Sn–Zn Dinuclear Cluster Constructed by a Sulfur-Contained Complex Unit
Source: Informa UK Limited
Synthesis, Crystal Structure and Properties of a New 3D Supramolecular Metal–Organic Framework with Stable Tunnels
Source: Springer Science and Business Media LLC
A square-pyramidal copper(II) complex with strong intramolecular hydrogen bonds: diaqua(N,N'-dimethylformamide-κO)bis[2-(diphenylphosphoryl)benzoato-κO]copper(II).
Source: (:unav)
Synthesis, Crystal Structure, and Properties of a Dinuclear Cu(I) Cluster
Source: Informa UK Limited
A photochromic dinuclear compound: aquatetrakis(μ-2,3-diphenylprop-2-enoato)bis(2,3-diphenylprop-2-enoato)ethanolbis(1,10-phenanthroline)dilanthanum(III).
Source: International Union of Crystallography (IUCr)

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.