A Comparative Study of the Effect of Water and Organic Solvents on 1,3-Dipolar Cycloaddition Reactions of Mesitonitrile Oxide with C-Sulfonyl- and Sulfanyl-Dithioformates

Ibrahim El-Sayed Chemistry Department, Faculty of Science, El-Menoufeia University, Shebin El-Koom, Egypt

Omar M. Ali Chemistry Department, Faculty of Science, El-Menoufeia University, Shebin El-Koom, Egypt

Mohamed A. Hawata Chemistry Department, Faculty of Science, El-Menoufeia University, Shebin El-Koom, Egypt

Sally Abou Hegazey Chemistry Department, Faculty of Science, El-Menoufeia University, Shebin El-Koom, Egypt

Abstract

1,3-Dipolar cycloadditions of the C-sulfonylated- and sulfanylated-dithioformates with mesitonitrile oxide occurred smoothly in organic and aqueous media to afford 1,4,2-oxathiazoles in good yields. The structures of these cycloadducts have been established via the analysis of NMR data and elemental analyses.

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Acknowledgments

Partial financial support from Danish International Development Agency (DANIDA) is highly appreciated.

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A Comparative Study of the Effect of Water and Organic Solvents on 1,3-Dipolar Cycloaddition Reactions of Mesitonitrile Oxide with C-Sulfonyl- and Sulfanyl-Dithioformates

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A Comparative Study of the Effect of Water and Organic Solvents on 1,3-Dipolar Cycloaddition Reactions of Mesitonitrile Oxide with C-Sulfonyl- and Sulfanyl-Dithioformates

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