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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 185, 2010 - Issue 5-6: A Tribute to the Chemistry of Professor Naomichi Furukawa
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Original Articles

Syntheses and Crystal Structures of [ClPh2Sn{E(Ph2SN)2}] (E = CH, N)

Takayoshi Fujii Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University, Chiba, Japan
,
Sayaka Iwata Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University, Chiba, Japan
,
Mitsuo Hirata Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University, Chiba, Japan
,
Kazuhiro Mizutani Department of Material Systems Engineering and Life Science, Faculty of Engineering, Toyama University, Toyama, Japan
,
Shintarou Sayama Department of Material Systems Engineering and Life Science, Faculty of Engineering, Toyama University, Toyama, Japan
,
Toshiaki Yoshimura Department of Material Systems Engineering and Life Science, Faculty of Engineering, Toyama University, Toyama, Japan
,
Tsukasa Nakahodo Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki, Japan
&
Takeshi Akasaka Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki, Japan
 show all
Pages 1046-1053 | Received 30 Nov 2008, Accepted 25 Dec 2008, Published online: 27 May 2010
 
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Abstract

Reaction of lithium salts, Li{E(SPh2N)2 } (E = CH (1− ), N(2− )) with diphenyltin dichloride in THF at –20 °C gave the corresponding tin-complexes [ClPh2Sn{E(Ph2SN)2}] (E = CH (3), N (4)) in good yields. The crystal structures of both compounds were determined by X-ray crystallographic analysis and showed to consist with a monomeric chelate structure that contains a distorted trigonal bipyramidal tin atom with a nitrogen and a chlorine atom in the axial sites. The chelated ligands in 3 and 4 adopt a boat and a twist boat conformation, respectively.

Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.

Acknowledgments

Dedicated to Professor Naomichi Furukawa on the occasion of his 70th birthday. This work was partially supported by a Grants-in-Aid for Scientific Research (No. 16750030 and 19550051) from the Ministry of Education, Culture, Sports, Science and Technology of Japan, and also supported by a grant from High Technology Research Center, College of Industrial Technology, Nihon University.

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