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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 186, 2011 - Issue 4: 18th International Conference on Phosphorus Chemistry (ICPC2010)
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II. Theoretical and Structural Chemistry

Kinetic Study of the Reaction of Tertiary Phosphines with Acrylic Acid in Aprotic Solvents

Alexey V. Salin Department of Chemistry, Kazan State University, Kazan, Russia
,
Alexandr A. Sobanov Department of Chemistry, Kazan State University, Kazan, Russia
,
Yulia V. Bakhtiyarova Department of Chemistry, Kazan State University, Kazan, Russia
,
Azat A. Khabibullin Department of Chemistry, Kazan State University, Kazan, Russia
,
Vladimir I. Galkin Department of Chemistry, Kazan State University, Kazan, Russia
&
Rafael A. Cherkasov Department of Chemistry, Kazan State University, Kazan, Russia
Pages 854-856 | Received 12 Apr 2010, Accepted 08 Jun 2010, Published online: 25 Apr 2011
 
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Abstract

The kinetics of the reaction of tertiary phosphines with acrylic acid in a series of aprotic solvents was studied by spectrophotometry. The data obtained suggest a stepwise mechanism of interaction including initial formation of zwitterionic intermediate followed by intermolecular proton transfer to the generated carbanionic center from the second molecule of acrylic acid.

Acknowledgments

The work is maintained by the joint Russian–American CRDF Program “Basic Research and High Education” (BRHE, grant REC-007).

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