Optically Active Cage P,N-Containing Cyclophanes Based on L-Menthylphosphine and Their Platinum (II) and Palladium (II) Complexes

Anna S. Balueva Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia

Svetlana N. Ignatieva Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia

Andrey A. Karasik Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia

Peter Lönnecke Institute of Inorganic Chemistry, Leipzig University, Leipzig, Germany

Eva-Marie Hey-Hawkins Institute of Inorganic Chemistry, Leipzig University, Leipzig, Germany

Oleg G. Sinyashin Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia

Abstract

We report here a synthesis of novel chiral P,N-containing cyclophanes with l-menthyl substituents on the phosphorus atoms and their platinum (II) and palladium (II) complexes.

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Acknowledgments

Financial support from RFBR and DFG (grants 09-03-91338-DFG_a, 09-03-99011_r_ofi) is gratefully acknowledged.

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Optically Active Cage P,N-Containing Cyclophanes Based on L-Menthylphosphine and Their Platinum (II) and Palladium (II) Complexes

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Optically Active Cage P,N-Containing Cyclophanes Based on L-Menthylphosphine and Their Platinum (II) and Palladium (II) Complexes

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