Stereoselective Synthesis of Novel 18- and 20-Membered P,N-Containing Macrocyclic Phosphine Ligands

Kirill B. Kanunnikov Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia

Roman N. Naumov Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia

Andrey A. Karasik Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia

Eva-Marie Hey-Hawkins Institut für Anorganische Chemie der Universität Leipzig, Leipzig, Germany

Oleg G. Sinyashin Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia

Abstract

We report here the stereoselective synthesis of novel macrocyclic tetraphosphines, based on the principles of covalent self-assembly.

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Acknowledgments

Financial support was received from RFBR (No. 10-03-00380), the president of the Russian Federation grant for the support of leading scientific schools (No. 3831.2010.3), and the Ministry of Education of the Russian Federation (state contract 02.740.11.0633).

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Stereoselective Synthesis of Novel 18- and 20-Membered P,N-Containing Macrocyclic Phosphine Ligands

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Stereoselective Synthesis of Novel 18- and 20-Membered P,N-Containing Macrocyclic Phosphine Ligands

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