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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 186, 2011 - Issue 4: 18th International Conference on Phosphorus Chemistry (ICPC2010)
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I. Synthesis and Applications in Catalysis

α-Phosphino Amino Acids: Synthesis, Structure, and Reactivity

Joachim Heinicke Institut für Biochemie–Anorganische Chemie, Universität Greifswald, Germany
,
Joanna Lach Institut für Biochemie–Anorganische Chemie, Universität Greifswald, Germany
,
Kaleswara R. Basvani Institut für Biochemie–Anorganische Chemie, Universität Greifswald, Germany
,
Normen Peulecke Institut für Biochemie–Anorganische Chemie, Universität Greifswald, Germany
,
Peter G. Jones Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Germany
&
Martin Köckerling Anorganische Chemie–Festkörperchemie, Universität Rostock, Germany
Pages 666-677 | Received 10 Jul 2010, Accepted 02 Aug 2010, Published online: 25 Apr 2011
 
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Abstract

One-pot three-component reactions of secondary or primary phosphines and primary amines with glyoxylic acid provide a wide variety of acyclic or cyclic phosphinoglycines, in the case of some chiral amines with high diastereoselectivity. The structure, hydrolysis, oxidation, coordination at M(CO)5 (M = Cr, Mo, W), and use in nickel-catalyzed ethylene oligomerization were studied.

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