A New Versatile Synthesis of Functionalized Phosphine Oxides—Efficient Ligands for Rare-Earth Metals Extraction

D. A. Tatarinov A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre, Russian Academy of Sciences, Kazan, Russian Federation; Kazan (Volga region) Federal University, Kazan, Russian Federation

V. F. Mironov A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre, Russian Academy of Sciences, Kazan, Russian Federation; Kazan (Volga region) Federal University, Kazan, Russian Federation

A. A. Kostin A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre, Russian Academy of Sciences, Kazan, Russian Federation; Kazan (Volga region) Federal University, Kazan, Russian Federation

A. V. Nemtarev A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre, Russian Academy of Sciences, Kazan, Russian Federation; Kazan (Volga region) Federal University, Kazan, Russian Federation

T. A. Baronova A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre, Russian Academy of Sciences, Kazan, Russian Federation

B. I. Buzykin A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre, Russian Academy of Sciences, Kazan, Russian Federation

Yu. G. Elistratova A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre, Russian Academy of Sciences, Kazan, Russian Federation

show all

Abstract

A new approach to the synthesis of 2-hydroxyaryl-alkenylphosphine oxides and dialkyl (diaryl)-(2-methyl-4-oxopent-2-yl)phosphine oxides was developed that involves an interaction of Grignard reagents with available benzo[e]-1,2-oxaphosphorinines and 1,2-oxaphospholene-2-oxide. This approach allows obtaining target compounds with a high yield. The synthesized phosphine oxides proved to be highly efficient extractants in the micellar extraction of some lanthanides from the nitric acid media.

Keywords:

Acknowledgments

The work was supported by the Russian Foundation for Basic Research and Tatarstan Academy of Sciences (grant No. 09-03-97007-r_a) and by a grant from the president of the Russian Federation (MK-1172.2010.3).

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

A New Versatile Synthesis of Functionalized Phosphine Oxides—Efficient Ligands for Rare-Earth Metals Extraction

Information for

Open access

Opportunities

Help and information

A New Versatile Synthesis of Functionalized Phosphine Oxides—Efficient Ligands for Rare-Earth Metals Extraction

Abstract

Acknowledgments

Reprints and Corporate Permissions

Academic Permissions

Related research

To cite this article:

Download citation

Information for

Open access

Opportunities

Help and information

Keep up to date

Your download is now in progress and you may close this window

Login or register to access this feature