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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 186, 2011 - Issue 4: 18th International Conference on Phosphorus Chemistry (ICPC2010)
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I. Synthesis and Applications in Catalysis

The Molecular Design of “Carcass”-Type Phosphoranes, Based on the Reaction of P(III)-Cyclic Derivatives and Unsaturated Activated Compounds

L. M. Abdrakhmanova A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre, Russian Academy of Sciences, Kazan, Russian Federation
,
V. F. Мironov A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre, Russian Academy of Sciences, Kazan, Russian Federation
,
T. P. Gryaznova A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre, Russian Academy of Sciences, Kazan, Russian Federation
,
S. A. Katsyuba A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre, Russian Academy of Sciences, Kazan, Russian Federation
&
M. N. Dimukhametov A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre, Russian Academy of Sciences, Kazan, Russian Federation
Pages 652-656 | Received 07 Jul 2010, Accepted 01 Sep 2010, Published online: 25 Apr 2011
 
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Abstract

The methodology for the synthesis of carcass-type (cage-like type) phosphoranes was developed, which allows us to obtain the products of the given structure with a high regio- and stereoselectivity in the result of cascade processes.

Acknowledgments

The work was supported by Russian Foundation for Basic Research (grant 10-03-00525).

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Related Research Data

A Novel N,P,C Cage Complex Formed by Rearrangement of a Tricyclic Phosphirane Complex: On the Importance of Non-covalent Interactions
Source: Wiley
Tandem dihetero-Diels–Alder and Huisgen cycloaddition reactions. Synthesis, crystal structure and hydrolysis of the novel cage phosphoranes
Source: Royal Society of Chemistry (RSC)
Synthesis, crystal structure and hydrolysis of novel isomeric cage (P–C/P–O)-phosphoranes on the basis of 4,4,5,5-tetramethyl-2-(2-oxo-1,2-diphenylethoxy)-1,3,2-dioxaphospholane and hexafluoroacetone
Source: Royal Society of Chemistry (RSC)

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