Reductive Diphosphene Formation From W(CO)5-Coordinated Dichlorophosphanes: Phosphorus, Sulfur, and Silicon and the Related Elements: Vol 186, No 4

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Abstract

A bis-[W(CO)₅]-coordinated (^tBu)₂diphosphene was prepared from the corresponding [W(CO)₅]-^tBuPCl₂ by treatment with LiAlH₄.

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Acknowledgments

This work was supported by the Swedish Research Council, the Göran Gustafsson Foundation, and Uppsala University through the U3MEC molecular electronics priority initiative.

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Reductive Diphosphene Formation From W(CO)₅-Coordinated Dichlorophosphanes

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Reductive Diphosphene Formation From W(CO)5-Coordinated Dichlorophosphanes

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Reductive Diphosphene Formation From W(CO)₅-Coordinated Dichlorophosphanes