Synthesis of Polycyclic Hexacoordinated Phosphorus Derivatives from Salicylaldehyde Diimines

Alexander R. Burilov A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, Russia

Ludmila K. Kibardina A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, Russia

Michael A. Pudovik A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, Russia

Svetlana A. Terent’eva A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, Russia

Olga N. Kataeva A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, Russia

Galina A. Chmutova A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, Russia

Vladimir A. Al’fonsov A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, Russia

Shamil K. Latypov A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, Russia

Oleg G. Sinyashin A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, Russia

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Abstract

A new approach to the synthesis of polycyclic hexacoordinated phosphorus derivatives was developed. It is based on the reaction of alkylene chlorophosphites with salicylaldehyde diimines without a base catalyst.

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Acknowledgments

The authors are grateful to the Russian Foundation for Basic Research for support of this work (grant no. 09-03-00029).

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Synthesis of Polycyclic Hexacoordinated Phosphorus Derivatives from Salicylaldehyde Diimines

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Synthesis of Polycyclic Hexacoordinated Phosphorus Derivatives from Salicylaldehyde Diimines

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