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The thermal stability of stannylated phosphanosilanes/germanes has been explored, where chlorostannane elimination should yield multiply bonded systems. Although destannylation occurs, the resulting products are hydrophosphanes and polymeric materials.
GRAPHICAL ABSTRACT
Financial support by the Austrian Science Fund (FWF) (P20575-N19), the Land Steiermark, and EU-COST Action CM 0802 (PhoSciNet) is gratefully acknowledged.
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