Catalytic Disproportionation of Methyltrichlorosilane by AL-MCM-41 to Prepare Dichlorodimethylsilane

Abstract

Al-MCM-41 samples with various Si/Al ratios were prepared and then used to disproportionate methyltrichlorosilane (MTS) to produce dichlorodimethylsilane (DMCS). The catalysts were characterized by FT-IR, X-ray powder diffraction (XRD), ²⁷Al magic angle spinning nuclear magnetic resonance (²⁷Al MAS NMR), inductively coupled plasma atomic emission spectroscopy (ICP-AES), and N₂ absorption–desorption. It reveals that all samples show the hexagonal structure of MCM-41 and exhibit large BET surface areas (over 842 m²·g⁻¹). FT-IR spectra of pyridine adsorption demonstrates that Al-MCM-41 samples have Lewis (L) and Brønsted (B) acidic sites, and the B acidic sites are stable in the temperature ranging from 423 to 623 K. The effects of aluminum content and temperature on the disproportionation reaction were also investigated. The results show that the Al-MCM-41 with the Si/Al ratio of 15:1 exhibits an excellent activity with 100% conversion of MTS and 47% selectivity of DMCS at 623 K under atmospheric pressure.

GRAPHICAL ABSTRACT

Keywords:

• Al-MCM-41
• methyltrichlorosilane
• catalytic disproportionation
• dichlorodi- methylsilane
• Lewis and Brønsted acidic sites

Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos. 21062013 and 20562007), the Foundation of Educational Department of Jiangxi Province and the Graduate Innovation Foundation of Jiangxi Province (No.YC09A032).