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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 188, 2013 - Issue 6
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Original Articles

Polymeric Three-Dimensional Crystal Structure of a Tributyltin(IV) Derivative with Acetylene Dicarboxylic Acid

Shabbir Hussain Department of Chemistry, GC University, Faisalabad, Pakistan
,
Saqib Ali Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan
,
Saira Shahzadi Department of Chemistry, GC University, Faisalabad, Pakistan
&
Corrado Rizzoli Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Parco Area delle Scienze 17/A, Parma, Italy
Pages 812-818 | Received 27 Apr 2012, Accepted 03 Jul 2012, Published online: 31 May 2013
 
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Abstract

A novel polymeric complex has been synthesized by refluxing disodium acetylene dicarboxylate with tributyltin chloride in dry methanol. The solid-state structure of the complex has been determined by single-crystal X-ray analysis. The tin(IV) metal exhibits distorted trigonal bipyramidal geometry. Each carboxylate group of the ligand acts in a bidentate fashion, linking adjacent metal atoms to produce polymeric chains, which are cross-linked into a three-dimensional network.

GRAPHICAL ABSTRACT

Acknowledgments

The first athor (SH) thanks the Higher Education Commission, Islamabad, Pakistan, for financial support under the PhD Fellowship Scheme Batch-IV (PIN Code: 074-3160-Ps4-362). Pakistan Science Foundation is acknowledged for partial support under the project PSF/Res/PGCU/Chem(436).

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