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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 188, 2013 - Issue 5
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Original Articles

Synthesis of Functionalized Phosphonates and Chromenes via Catalyst-Free Multicomponent Reactions in Water

Zinatossadat Hossaini Department of Chemistry, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran
,
Faramarz Rostami Charati Department of Chemistry, Faculty of Science, Gonbad Kavous University, Gonbad, Iran
&
Mahboubeh Ghasemian Department of Chemistry, North of Tehran Branch, Islamic Azad University, Tehran, Iran
Pages 555-560 | Received 16 Jun 2012, Accepted 17 Aug 2012, Published online: 31 May 2013
 
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Abstract

Stable derivatives of phosphonates were prepared using multicomponent reactions of dialkyl acetylenedicarboxylate with 4-hydroxycumarin in the presence of trimethyl or triphenyl phosphite in good yields. Chromene derivatives were produced by using triethyl phosphite and dialkyl acetylenedicarboxylate in the presence of 4-hydroxycumarin in excellent yields.

GRAPHICAL ABSTRACT

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