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Original Articles

Application of “Click” Cycloaddition for Synthesis of New Sulfur-Containing Oligomeric System

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Pages 496-498 | Received 25 Sep 2012, Accepted 25 Sep 2012, Published online: 29 May 2013
 

Abstract

The efficient synthesis of new sulfur-containing macrocycles via “click”-type alkyne–azide cycloaddition was described. Preliminarily, under aqueous conditions (water–methanol) using CuSO4/sodium ascorbate as a source of Cu(I), the yields of the products were very poor. Using the Cu(I) in nonaqueous solution (MeCN), the yields of the products grow significantly (approx. 50%).

GRAPHICAL ABSTRACT

Acknowledgments

Authors acknowledge financial support from National Science Center (NCN, Grant No. 2011/01/B/ST5/ 06613).

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