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Abstract
The chemistry of bis(sulfoxides) is discussed from two starting materials, (Ss,Ss)-bis-p-tolylsulfinylmethane and (Ss,Ss)-bis-p-tolylsulfinyl alkylidenes. Reactions presented include Michael additions, ionic-radical crossover processes and coordination complexes formations.
GRAPHICAL ABSTRACT
Acknowledgments
The authors thank CNRS, UPMC, the ANR BLAN “Radicaux Verts” and “CREDOX”, DGA, Fondation de Gif, and IUF for financial support. They also thank Lise-Marie Chamoreau, Partrick Herson, and Jacqueline Vaisserman (UPMC) for the X-ray structure determinations.
