Novel Phosphorus-Containing Bicyclic Phosphonate on the Basis of 1,4-Hydroquinone

Liudmila K. Kibardina State Budgetary-Funded Institution of Science, A. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences, Arbuzov Str. 8, Kazan 420088, Russian Federation

Yulia M. Sadykova State Budgetary-Funded Institution of Science, A. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences, Arbuzov Str. 8, Kazan 420088, Russian Federation

Natalia V. Dalmatova Kazan National Research Technological University, K. Marksa Str., 68, Kazan 420015, Russian Federation

Alexander R. Burilov State Budgetary-Funded Institution of Science, A. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences, Arbuzov Str. 8, Kazan 420088, Russian Federation

Michael A. Pudovik State Budgetary-Funded Institution of Science, A. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences, Arbuzov Str. 8, Kazan 420088, Russian Federation

Abstract

Condensation of 1,4-hydroquinone with 2-ethoxyvinyl phosphonic acid dichloroanhydride in boiling toluene in the presence of trifluoroacetic acid results in the formation of the new bicyclic phosphonate of carcass structure with one endocyclic Р–С bond, which is obtained in high yield.

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Acknowledgments

This work was supported by the Russian Foundation for Basic Research (grant 11-03-00416-а).

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Novel Phosphorus-Containing Bicyclic Phosphonate on the Basis of 1,4-Hydroquinone

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Novel Phosphorus-Containing Bicyclic Phosphonate on the Basis of 1,4-Hydroquinone

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