Novel Biomimetic Cyclic P,N-Ligands. Lability of P-CH₂-N Fragment: Problem or Advantage?

Andrey A. Karasik Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia

Elvira I. Musina Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia

Anna S. Balueva Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia

Oleg G. Sinyashin Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia

Abstract

The lability of the P-CH₂-N fragment results in thermodynamically controlled processes of stereoconversions, substituents exchange, and ring transformations of P,N-containing hetero- and macrocycles.

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Acknowledgments

This work was supported by RFBR (No. 10–03-00380-а, 11–03-12152-ofi_m), the President's of RF grant for leading scientific schools (No. NSh-6667.2012.3), and the VW Foundation (No. 85 625).

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Novel Biomimetic Cyclic P,N-Ligands. Lability of P-CH₂-N Fragment: Problem or Advantage?

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Novel Biomimetic Cyclic P,N-Ligands. Lability of P-CH₂-N Fragment: Problem or Advantage?