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Original Articles

Stable N-Phosphorylated Triazol-5-Ylidenes

, , , , , & show all
Pages 254-255 | Received 15 Sep 2012, Accepted 15 Oct 2012, Published online: 08 May 2013
 

Abstract

Novel N-phosphorylated triazolium salts have been synthesized. They react with sodium bis(trimethylsilyl)amide to produce new stable N-phosphorylated triazole-5-ylidenes, which rearrange to C-phosphorylated triazoles under heating. The formation of two silver carbene complexes is described. Representative carbene and carbene complex structures were determined by X-ray study.

GRAPHICAL ABSTRACT

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