Abstract
Novel N-phosphorylated triazolium salts have been synthesized. They react with sodium bis(trimethylsilyl)amide to produce new stable N-phosphorylated triazole-5-ylidenes, which rearrange to C-phosphorylated triazoles under heating. The formation of two silver carbene complexes is described. Representative carbene and carbene complex structures were determined by X-ray study.
GRAPHICAL ABSTRACT
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