Effective Modular Assembling of Novel Ligands Starting from (Thio)Phosphorylated Anilines

Abstract

A series of novel oligodentate ligands has been designed by the modular assembly of ortho-(thio)phosphorylated anilines with a range of commercially available carbonyl compounds. The new ligands readily form complexes with a series of metal ions (Pd(II), Cu(II), Ni(II), and Re(I)) both in neutral and deprotonated forms, providing OO, SN, ONO, SNO, SNS, SNN, and ONN donor sets. The structure and composition of the resulting complexes depend on the nature and mutual disposition of the donating groups as well as on the reaction conditions.

GRAPHICAL ABSTRACT

Keywords:

• Oligodentate phosphorus ligands
• modular assembling
• transition metal complexes

Acknowledgments

This work was supported by the Russian Foundation for Basic Research (project no. 12-03-00793-a).