Advanced search
Publication Cover
Phosphorus, Sulfur, and Silicon and the Related Elements Volume 188, 2013 - Issue 1-3: 19th International Conference on Phosphorus Chemistry (ICPC-2012) Rotterdam, 8–12 July, 2012
Submit an article Journal homepage
69
Views
2
CrossRef citations to date
0
Altmetric
Original Articles

Polarity and Conformational Analysis of Secondary Phosphine Selenides

Yana A. Vereshchagina Kazan Federal University, Kremlevskaya Str. 18, Kazan, 420008, Russia
,
Eleonora A. Ishmaeva Kazan Federal University, Kremlevskaya Str. 18, Kazan, 420008, Russia
,
Denis V. Chachkov Kazan Branch of Joint Supercomputer Center of Russian Academy of Sciences, Kazan, Russia
,
Nina K. Gusarova Irkutsk A. E. Favorsky Institute of Chemistry, Siberian Branch of Russian Academy of Sciences, Irkutsk, Russia
,
Svetlana F. Malysheva Irkutsk A. E. Favorsky Institute of Chemistry, Siberian Branch of Russian Academy of Sciences, Irkutsk, Russia
&
Alsu Z. Alimova Kazan Federal University, Kremlevskaya Str. 18, Kazan, 420008, Russia
Pages 95-99 | Received 30 Aug 2012, Accepted 17 Oct 2012, Published online: 08 May 2013
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

The polarities of bis(2-phenylethyl) and bis(2-phenylpropyl) phosphine selenides were determined and conformational analysis of these phosphine selenides was carried out by the method of dipole moments, IR spectroscopy, and quantum chemical calculations. They exist as an equilibrium of several conformers, and the preferred conformers have gauche orientation of the P = Se and Csp3 – Csp3 bonds.

GRAPHICAL ABSTRACT

Acknowledgments

This work was supported by the Russian Foundation for Basic Research (Grant No. 10-03-00098-a).

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.