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Original Articles

Unexpected Transformation of a Schiff Base Pyridine N-Oxide in the Presence of Pr(NO3)3 · 6H2O

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Pages 111-115 | Received 04 Sep 2012, Accepted 19 Oct 2012, Published online: 08 May 2013
 

Abstract

The synthesis of (E)-((6-(((3-hydroxy-4-methoxybenzylidene)amino)methyl)-N-oxide-pyridin-2-yl)methyl)diphenylphosphine oxide 1 and its unexpected transformation during efforts to study the coordination chemistry with Pr(NO3)3·6H2O are described.

GRAPHICAL ABSTRACT

Acknowledgments

Financial support for this study at the University of New Mexico was provided by the Division of Chemical Sciences, Geosciences and Biosciences, Office of Basic Energy Sciences, and U.S. Department of Energy (Grant DE-FG02-03ER15419 (R.T.P). In addition, funds from the National Science Foundation assisted with the purchases of the X-ray diffractometer (CHE-0443580) and NMR spectrometers (CHE-0840523 and -0946690).

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