Abstract
The reaction products of PCl5 with 2,6-dimesityl-aniline and with naphthalene-1,5-diamine are 4-chloro-2,6-dimesityl-aniline and (2,4,6,8-tetrachloronaphthalene-1,5-diyl)bis(phosphorimidic trichloride), respectively, and were characterized by X-ray crystallographic analyses. The phosphazene shows π-stacking, extremely large C–N–P angles, and extremely short P–N distances.
GRAPHICAL ABSTRACT
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